Product ID:TRANS-2-BUTENAL, 0-228
MSDS Date:09/01/1988
FSC:6810
NIIN:00N066041
MSDS Number: CBWFH

CHEM SERVICE INC

WEST CHESTER, PA 19381
US

Emergency Phone: 215-692-3026

Info Phone: 215-692-3026

Cage: 84898

CHEM SERVICE, INC

599 WEST CHESTER, PA 19301-9650 US

Telephone: 610-692-3026

Cage: 8Y898

CROTONALDEHYDE, (E)-; (TRANS-2-BUTENAL) (SARA 302)

CAS: 123-73-9

RTECS: GP9625000

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:LD50:(RAT) 300 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ALL CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT! LACHYRMATOR-CAUSES
SEVERE EYE IRRITATION. CAN BE FATAL IF INHALED! MAY BE FATAL IF
SWALLOWED! CAN BE FATAL IF ABSORBED THR OUGH SKIN! CAN CAUSE
EYE/SKIN IRRITATION. DUST &/OR VAPORS CAN CAUSE IRRITATION TO
RESPIRATORY TRACT. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CAN BE IRRITATING TO MUCOUS MEMBRANES.
CAN CAUSE EDEMA-SWELLING OF TISSUES. EXTREMELY DESTRUCTIVE OF
MUCOUS MEMBRANES &/OR UPPER RESPIRATORY TRACT. THIS COMPOUND IS
CONSIDERED TO BE TOXIC.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMED . EYES:FLUSH CONTINUOUSLY W/WATER FOR AT
LST 15-20 MINS. SKIN:FLUSH W/WATER FOR 15-20 MINS. IF NO BURNS HAVE
OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. REMOVE & WASH CONTAM
CLTHG. GET MED ATTN IF NEC. INHAL:REMOVE PATIENT TO FRESH AIR.
ADMIN OXYG IF PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT HAS
STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS IN CARDIAC ARREST
ADMIN(SUPDAT)

Flash Point:55.4F,13.0C
Lower Limits:2.1%
Upper Limits:15.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS IS A FLAMMMABLE CHEMICAL.

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR
MATERIAL. SWEEP UP & PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR
DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT W/SKIN, EYES & CLTHG.
KEEP TIGHTLY CLSD & STORE IN A COOL, DRY PLACE. STORE UNDER
NITROGEN & REFRIGERATION. STORE ONLY W/COMPAT CHEMS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HANDLE THIS CHEM/ITS CNTNR. THIS PROD IS FURNISHED FOR LAB USE
ONLY! MFR'S PRODS MAY NOT BE USED AS DRUGS, COSMETICS,
AGRICULTURAL/PESTICIDAL PRO DS, FOOD ADDITIVES/AS HOUSEHOLD CHEMS.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USE APPROPRIATE OSHA/MSHA SAFETY EQUIPMENT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
FIRST AID PROC:CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED
ASSISTANCE HAS ARRIVED. NOTE:AN ANTIDOTE IS A SUBSTANCE INTENDED TO
COUNTERACT EFT OF A POIS. IT SHOULD BE ADMINISTERED ONLY BY
MD/TRAIN ED EMERGENCY PERS. MED ADVICE CAN BE OBTAINED FROM A
POISON CONTROL CENTER. EYE PROT:& FULL LENGTH FACESHIELD .

Boiling Pt:B.P. Text:219F,104C
Melt/Freeze Pt:M.P/F.P Text:-106F,-77C
Vapor Pres:30 @ 20C
Spec Gravity:0.853
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/CAUSTICS, AMMONIA &/OR AMMONIUM HYDROXIDE, STRONG ACIDS,
STRONG OXIDIZING AGENTS. REACTS W/AMINES.
Stability Condition to Avoid:HANDLE & STORE UNDER NITROGEN. SENSITIVE
TO HEAT.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
Conditions to Avoid Polymerization:MAY POLYMERIZE UPON STANDING.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER
& SCRUBBER.

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particular situation.